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Metal-organic framework UiO-66 membranes

Xinlei Liu

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 216-232 doi: 10.1007/s11705-019-1857-5

Abstract: Metal-organic frameworks (MOFs) have emerged as a class of promising membrane materials.

Keywords： membrane     metal-organic framework     UiO-66     separation    

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Optimizing iodine capture performance by metal–organic framework containing with bipyridine units

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 4,   Pages 395-403 doi: 10.1007/s11705-022-2218-3

Abstract: The adsorptive capture of radioactive iodine by metal–organic frameworks (MOFs) has risen to prominence

Keywords： metal–organic framework     iodine     adsorption     nuclear waste     environmental remediation    

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Nickel-based metal−organic framework-derived whisker-shaped nickel phyllosilicate toward efficiently

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10,   Pages 1493-1504 doi: 10.1007/s11705-022-2168-9

Abstract: Metal−organic framework-derived materials have attracted significant attention in the applications ofIn this work, the rod-like nickel-based metal−organic frameworks were first synthesized and subsequently

Keywords： metal−organic framework     nickel phyllosilicate     whisker     epoxy resin     mechanical response     tribological    

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Fluorescence detection of phosphate in an aqueous environment by an aluminum-based metal-organic framework

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 12, doi: 10.1007/s11783-022-1594-8

Abstract:

● A novel Al-MOF was successfully synthesized by a facile solvothermal method.

Keywords： Fluorescence     Metal-organic framework     Phosphate     Detection     Al-MOF    

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A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 3, doi: 10.1007/s11783-023-1633-0

Abstract:

● pz-UiO-66 was synthesized facilely by a solvothermal method.

Keywords： Pyrazine     Metal-organic frameworks     Copper removal     Strong acidity     High selectivity    

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Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1550-1560 doi: 10.1007/s11705-021-2104-4

Abstract: nanoparticle decorated N-doped carbons (Co@NC) are synthesized by the pyrolysis of a cobalt covalent organicframework under an inert atmosphere.

Keywords： cobalt embedment     N-doped carbons     covalent organic framework     oxygen reduction     Zn-air battery    

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Conversion of CO into CO by high active and stable PdNi nanoparticles supported on a metal-organic framework

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1139-1148 doi: 10.1007/s11705-021-2111-5

Abstract: The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd+ Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution of PdNi nanoparticles, and lower dissociation and desorption barriers. Comparison of the catalysts synthesized by MIL-101(Cr) and MIL-101-NH2(Cr) as the supports of metals showed that Pd/MIL-101-NH2(Cr) outperforms Pd/MIL-101-(Cr) because of the higher electron density of Pd resulting from the electron donor ability of the NH2 functional group. However, the same activities were observed for Pd70Ni30/MIL-101(Cr) and Pd70Ni30/MIL-101-NH2(Cr), which is due to a less uniform distribution of Pd nanoparticles in Pd70Ni30/MIL-101-NH2(Cr) originated from amorphization of MIL-101-NH2(Cr) structure during the reduction process. In contrast, Pd70Ni30/MIL-101(Cr) revealed the stable structure and activity during reduction and CO oxidation for a long time.

Keywords： CO oxidation     heterogeneous catalysis     metal-organic framework     NH2 functional group     PdNi    

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Hydrophobic nanocellulose aerogels with high loading of metal-organic framework particles as floating

Jiajia Li, Shengcheng Zhai, Weibing Wu, Zhaoyang Xu

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 5,   Pages 1158-1168 doi: 10.1007/s11705-020-2021-z

Abstract: In this paper, we employed a facile approach to prepare flexible and porous metal-organic frameworksThese prepared aerogels showed excellent oil/water selectivity and high capacity to adsorb oil and organic

Keywords： cellulose nanofibers     aerogels     metal-organic framework     oil-adsorption    

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Room-temperature hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 12,   Pages 1782-1792 doi: 10.1007/s11705-022-2220-9

Abstract: on nitrogen-doped carbon nanoneedles (Ni@NCNs) were prepared by simple pyrolysis of Ni-based metal–organic-framework

Keywords： nitrobenzenes     room-temperature hydrogenation     Ni nanoparticles     nitrogen-doped carbon nanoneedles     metal–organic-framework    

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Engineering zirconium-based metal-organic framework-801 films on carbon cloth as shuttle-inhibiting interlayers

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 4,   Pages 511-522 doi: 10.1007/s11705-021-2068-4

Abstract: Herein, a novel zirconium-based metal-organic framework-801 film on carbon cloth was developed as a versatile

Keywords： lithium-sulfur batteries     metal-organic framework-801 film     interlayer     shuttle effect    

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Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 9,   Pages 1387-1398 doi: 10.1007/s11705-022-2154-2

Abstract: Overall, the approach depicts an efficient model for integrating metal-organic frameworks on cellulosenanofibers to improve metal-organic framework recovery performance with potentially broad applications

Keywords： UiO-66-NH2     cellulose nanofibers     rose bengal     adsorption     mechanism    

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Metal-organic framework-based CO

Yujie Ban, Meng Zhao, Weishen Yang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 2,   Pages 188-215 doi: 10.1007/s11705-019-1872-6

Abstract: Metal-organic frameworks (MOFs), as a novel type of porous materials, are being generated at a rapidIn this review, we illustrate a conceptional framework from material design and membrane separation application

Keywords： CO2 capture     CO2-philic MOFs     crack-free membranes    

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Decoding and quantitative detection of antibiotics by a luminescent mixed-lanthanide-organic framework

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 12, doi: 10.1007/s11783-022-1589-5

Abstract:

● A series of mixed-LOFs and portable LOF-fibers were synthesized.

Keywords： Antibiotics     Sensor     Luminescence     Lanthanide-organic frameworks    

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Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 939-949 doi: 10.1007/s11705-022-2152-4

Abstract: microparticles containing hierarchical porous structures integrated with highly accessible catalytic metal organicframeworks for efficient degradation of organic contaminants.framework nanorods as the nanocatalysts.framework nanorods for enhanced degradation of organic contaminants via a heterogeneous Fenton-likesimple and general strategy to flexibly combine hierarchical porous structures and catalytic metal-organic

Keywords： metal-organic framework     polymer microparticle     nanocatalyst     decontamination     organic contaminant    

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Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 594-602 doi: 10.1007/s11705-017-1668-5

Abstract: A mild deposition method was used to fabricate Mn-based catalysts on a UiO-66 carrier for the selective catalytic reduction of NO by NH (NH -SCR). The catalyst with 8.5 wt-% MnO loading had the highest catalytic activity for NH -SCR with a wide temperature window (100–290 °C) for 90% NO conversion. Characterization of the prepared MnO /UiO-66 catalysts showed that the catalysts had the crystal structure and porosity of the UiO-66 carrier and that the manganese particles were well-distributed on the surface of the catalyst. X-ray photoelectron spectroscopy analysis showed that there are strong interactions between the MnO and the Zr oxide secondary building units of the UiO-66 which has a positive effect on the catalytic activity. The 8.5 wt-% MnO catalyst maintained excellent activity during a 24-h stability test and exhibited good resistance to SO poisoning.

Keywords： metal-organic framework     selective catalytic reduction     manganese oxides     deNOx     SO   

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Title Author Date Type Operation

Metal-organic framework UiO-66 membranes

Xinlei Liu

Journal Article

Optimizing iodine capture performance by metal–organic framework containing with bipyridine units

Journal Article

Nickel-based metal−organic framework-derived whisker-shaped nickel phyllosilicate toward efficiently

Journal Article

Fluorescence detection of phosphate in an aqueous environment by an aluminum-based metal-organic framework

Journal Article

A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

Journal Article

Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

Journal Article

Conversion of CO into CO by high active and stable PdNi nanoparticles supported on a metal-organic framework

Journal Article

Hydrophobic nanocellulose aerogels with high loading of metal-organic framework particles as floating

Jiajia Li, Shengcheng Zhai, Weibing Wu, Zhaoyang Xu

Journal Article

Room-temperature hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed

Journal Article

Engineering zirconium-based metal-organic framework-801 films on carbon cloth as shuttle-inhibiting interlayers

Journal Article

Integrating of metal-organic framework UiO-66-NH2 and cellulose nanofibers mat for high-performance adsorption

Journal Article

Metal-organic framework-based CO

Yujie Ban, Meng Zhao, Weishen Yang

Journal Article

Decoding and quantitative detection of antibiotics by a luminescent mixed-lanthanide-organic framework

Journal Article

Hierarchical porous metal-organic frameworks/polymer microparticles for enhanced catalytic degradationof organic contaminants

Journal Article

Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

Journal Article